Shaped plastic articles having replicated microstructure surfaces

ABSTRACT

An article comprising a shaped, plastic layer or body comprising crosslinked polymer with hard and soft segments or moieties and having a microstructure-bearing surface is prepared by a process comprising filling a mold master, bearing or encoded with the microstructure to be replicated, with a fluid, castable, one-part, preferably solvent-free, radiation addition-polymerizable, crosslinkable, synthetic, organic oligomeric composition (or precursors thereof) having &#34;hard&#34; segments and &#34;soft&#34; polysiloxane segments, exposing the resulting case composition to radiation, preferably actinic radiation such as ultraviolet radiation, and thereby forming said article, e.g., a retroreflective cube-corner sheeting, Fresnel lens or video disc.

This a division of application Ser. No. 104,862, field Dec. 18, 1979,which is a division of Ser. No. 926,325, filed July 20, 1978, now U.S.Pat. No. 4,576,850.

This invention relates to the replication of surfaces bearingmicrostructure. In another aspect it relates to shaped plastic articles,such as retroreflecting cube-corner sheeting, Fresnel lens elements,diffraction gratings, video discs, and ophthalmic lenses, havingreplicated microstructure-bearing surfaces, and to a process for thepreparation of the articles. In another aspect, it relates to novelcastable radiation curable oligomers, a process for their preparation,and the use of such material in making said replicated plastic articles.

Many materials, techniques and processes have been proposed, patented orused for replicating various microstructure-bearing surfaces in the formof embossed, cast or molded plastic articles, e.g., see J. ofAppliedPhysics, Vol. 45, No. 10, p. 4557, Oct. 1974. Some of these havebeen of practical value though of limited application in many instanceswhile others have been found wanting as impractical, especially wherethe object has been high fidelity and durability of replication or massproduction capability. In many cases, the progress in this art has beenstymied by lack of suitable replicating materials.

For example, in the area of retroreflective cube-corner sheetings, usesas traffic signs and the other applications where light reflection isused for traffic direction and safety, U.S. Pat. No. 3,689,346 (Rowland)discloses a process for the continuous replication of such articles bydepositing a crosslinkable, partially polymerized resin, such as certainacrylic acid ester resins, on a negative molding surface to bereplicated, and exposing the resin to actinic light or heat to solidifythe resin. The resins used typically exhibited relatively high levels ofshrinkage upon solidifying or curing, thus giving rise to opticalimperfections in the cube-corner microstructure, that is, changes in theangles between the faces of the cube-corner which produce lightscattering rather than the desired maximum retroreflectivity. Attemptsto overcome such shortcomings are described in U.S. Pat. No. 3,935,359(Rowland) which discloses filling further resin in the void resultingfrom the shrinkage, and U.S. Pat. No. 3,980,393 (Heasley et al) whichdiscloses using a lens system in conjunction with the cube-cornerstructure in order to compensate for the shrinkage. Such modificationsare, of course, costly and demonstrate a need for replicating materialswhich do not significantly shrink and so cause optical imperfections inthe replication.

An example where plastics have been used in replication of opticalsurfaces or elements in U.S. Pat. No. 3,931,373 (Beattie) whichdiscloses replicating ophthalmic lenses from plastic compositions, suchas methyl methacrylate, by use of a replicating mold made of certainpolymeric materials, such as certain copolymers of styrene and methylmethacrylate, to prevent distortion of lenses during cure. French Pat.No. 2,247,329 discloses making replicas of video discs usingultra-violet radiation curable acrylics and epoxides. U.S. Pat. No.3,334,958 (Appeldorn) discloses Fresnel lens elements stamped frompolymerized methyl methacrylate using molds made from machined masterlenses.

Other U.S. patents disclosing replication of various articles usingplastic compositions are U.S. Pat. Nos. 2,310,790 (Jungerson), 2,482,598(Roos), 3,565,978 (Folger et al), 3,190,947 (Norcros), 3,369,949(Forrest) 3,667,946 (Sturderant), 2,524,862 (White); the replicationprocess of these patents require high molding temperatures or pressureswhich cause loss of fidelity in the replicated structure, use ofsolvents which require a long time to evaporate, long cure cycles,curable materials which have a limited "pot" life, or result inreplicated articles having limited toughness and dimensional stabilityand with severe shrinkage.

Though oligomers or cured polymers with "hard" and "soft" segments orblocks have been disclosed in the prior art, e.g., see "BlockCopolymers", Allport and Janes, published by Wiley & Sons, N. E. Chap.8C, (1973). "Polymer Blends & Copolymers", Manson & Sperling,publishedby Plenum Press, N.Y., p. 153-166, (1976), "Polymer Engineering& Science", Vol. 11, No. 4, p. 369, (1971), "Encyclopedia of PolymerScience & Technology", Kirk-Othmer, Suppl., Vol. 1, p. 521-543 (1976,and U.S. Pat. Nos. 3,560,417 (Pizzi et al) and 4,077,932 (Columbus),those materials have not been disclosed as useful in making shapedplastic articles comprising crosslinked polymer and having replicatedmicrostructure surfaces.

Briefly, in one aspect, this invention provides an article comprising ashaped, plastic, monolithic layer (or body) comprising certaincrosslinked polymer and having one or more, like or different,replicated microstructure-bearing surfaces. An example of such articleis a traffic control sign comprising a layer in the form of aself-supporting or free film or sheet of said crosslinked polymer andhaving on one side a microstructure-bearing surface in the form of areplicated array of retroreflective cube-corners, the other side ofwhich sheet can be replicated "flat" surface. Such articles are preparedby a process comprising filling a mold master, bearing themicrostructure to be replicated, with a fluid, castable, one-part,preferably solvent-free, radiation addition-polymerizable,crosslinkable, oligomeric composition (or precursors thereof) havingboth "hard" segments and "soft" polysiloxane segments, exposing theresulting cast composition to radiation, preferably actinic radiationsuch as ultraviolet radiation, and thereby forming said article. Saidprocess lends itself to rapid, mass production of such articles with noadverse environmental impact because no or only a mirror amount ofsolvent or other volatiles are evolved and it can be carried out atambient temperatures and pressures. The process also lends itself toreplication of articles with microstructure comprising utilitariandiscontinuities, such as projections and depressions, which are readilyreleased from the mold master without loss of the detail of the masterand with retention of the replication of such detail under a widevariety of conditions during use. The articles can be formed with a widevariety of desired properties, such as toughness, flexibility, opticalclarity or homogenity, and resistance to common solvents, themicrostructure of such articles having high thermal dimensionalstability, resistance to abrasion and impact, and integrity even whenthe articles are bent, e.g., 180°. The physical properties of thecrosslinked polymer can be varied by proper selection of the oligomriccomposition. The tensile strengths of the polymer can be varied from 70to 700 kg/cm², the modulus of elasticity can be varied from 140 to14,000 kg/cm², and the elongation-to-break can be varied from 5 to 300%.The optical homogenity of the polymer is manifested by at least 91%transmission of light, haze of less than 5%, and birefringence, Δn, ofless than 0.002, and the flexibility is manifested by desirable dynamicshear moduli over a wide temperature range, e.g., 23° to 120° C.

FIG. 1 is a plot of the dynamic shear moduli of illustrative plasticsused in making plastic articles of this invention;

FIG. 2 is an isometric view of replicated diffraction gratings of thisinvention;

FIG. 3 is a plan view of replicated array of cube-corner retroreflectiveelements of this invention;

FIG. 4 is an elevation section of FIG. 3 taken along 4--4;

FIG. 4A is an elevation section of a modified retroreflective sheetingemploying the array of FIG. 4;

FIG. 5 is a diagrammatic view of a cube-corner element;

FIG. 6 is an isometric view of a sheet of replicated linear Fresnellenses of this invention;

FIG. 7 is an isometric view of a replicated video disc of thisinvention;

FIG. 8 is an enlarged view of a portion of FIG. 7;

FIG. 9 is a schematic diagram of apparatus useful in making a sheet ofcube-corner element of FIGS. 3 and 4; and

FIGS. 10A-10I are diagrams of illustrative profiles of variousreplicated microstructures of this invention.

The term "microstructure", used herein in the context of a shapedarticle having a surface bearing microstructure, means the configurationof a surface which depicts or characterizes the predetermined desiredutilitarian purpose or function of said article. Discontinuities, suchas projections and indentations, in the surface will deviate in profilefrom the average profile or center line drawn through the microstructuresuch that the sum of the areas embraced by the surface profile above theline is equal to the sum of those areas below the line, said line beingessentially parallel to the nominal surface (bearing the microstructure)of the article. The heights of said deviations will be ±0.005 μm to ±750μm through a representative characteristic length of the surface, e.g.,1 to 30 cm. Said average profile, or center line, can be plano, concave,convex, aspheric or combinations thereof. Articles where said deviationsare of low order, e.g., from ±0.005 μm to 0.1 μm or, preferably, to±0.05 μm, and said deviations are of infrequent or minimal occurrence,i.e., the surface is free of any significant discontinuities, are thosewhere the microstructure-bearing surface is an essentially "flat" or"perfectly smooth" surface, such articles being useful, for example, asprecision optical elements or elements with a precision opticalinterface, such as ophthalmic lenses. Articles where said deviations areof said low order and of frequent occurrence are those, for example,bearing utilitarian discontinuities, as in the case of articles havinganti-refective microstructure. Articles where said deviations are ofhigh order, e.g., from ±0.1 μm to ±750 μm, and attributale tomicrostructure comprising a plurality of utilitarian discontinuitieswhich are the same or different and spaced apart or contiguous in arandom or ordered manner, are articles such as retroreflectivecube-corner sheeting, linear Fresnel lenses, and video discs. Themicrostructure-bearing surface can contain utilitarian discontinuitiesof both said low and high orders. The microstructure-bearing surface maycontain extraneous or non-utilitarian discontinuities so long as theamounts or types thereof do not significantly interfere with oradversely affect the predetermined desired utilities of said articles.It may be necessary or desirable to select a particular oligomericcomposition whose shrinkage upon curing does not result in saidinterfering extraneous discontinuities, e.g., a composition whichshrinks only 2 to 6%.

The above described profiles and the dimensions and spacing of saiddiscontinuities are those discernible by an electron microscope at 1000×to 100,000× or an optical microscope at 10× to 1000×.

In FIGS. 10A-10I, various illustrative profiles of replicatedmicrostructure-bearing surfaces are shown. The profile of FIG. 10A isplano, free of utilitarian discontinuities, and is illustrative of themicrostructure of an ophthalmic lens or optical flat. The profiles ofFIGS. 10B and 10C have spaced-apart utilitarian disciontinuities whichin FIGS. 10B are in the form of projection or raised areas 21 and inFIG. 10C are in the form of depressions or indentations 22, suchprofiles being illustrative, for example, of microstructure present onvideo discs. FIGS. 10D and 10E depict profiles with a plurality ofcontiguous, utilitarian discontinuities, such profiles beingillustrative, for example, of species of anti-reflective surfaces. FIG.10F depicts a profile with a plurality of closely spaced arcs, e.g.,hemispherical, and is illustrative of microstructure in the form ofutiliarian lenslets, e.g., a replicated beaded layer which can be vaporcoated with specular light reflecting material to provide aretroreflective sheet. FIG. 10G depicts a profile with individualcontiguous utilitarian discontinuities in the form of projections 23 oflike size and shape, and is illustrative of cube-corner retroreflectivemicrostructure made up of trihedral prism elements. FIG. 10H depicts aprofile with utiliarian discontinuities in the form of alternating steps24 and lands 25, such a profile being illustrative of a linear Fresnellens. And FIG. 10I depicts a profile which is a combination of the typesillustrated in FIGS. 10C and 10H, the lands 26 being "rough" due to loworder utilitarian discontinuities, such a profile being illustrative ofa linear Fresnel lens with antireflective microstructure.

Radiation addition-polymerizable, crosslinkable oligomeric compositionsuseful in making said shaped articles of this invention compriseradiation addition-polymerizable, oligomers or prepolymers having (1)one or more like or different "hard" (rigid) segments ("H"), vis., mono-or poly- and preferably di-valent moieties containing one or morecarbocyclic and/or heterocyclic groups and preferably difunctionallinking groups with hydrogenbonding capabilities, e.g., carbonyldioxy,--OC(O)O--, carbamato, --NHC(O)O--, ureylene, --NHCONH--, amido,--NHCO--, and oxy, --O--, said moieties, when their valences aresatisfied by protons, having at least one major transition temperatureabove 250° K., preferably above 350° K., said transition being a glasstransition temperature or crystalline melting point, such as are usuallydetected by differential thermal analysis or thermomechanical analysis,(2) one or more like or different "soft" (flexible) segments ("S"),viz., poly-valent polysiloxane moieties which have a number averagemolecular weight in the range of about 500 to 5000 and each of which inthe form of homopolymer has a glass transition temperature below 250°K., and (3) one or more like or different monovalent moieties ("E")containing a radiation sensitive, addition-polymerizable, functionalgroup such as acrylyl, methacrylyl, allyl or vic-epoxy group. Theamounts of "H", "S" and "E" segments or moieties in said oligomericcomposition are such that the radiation-cured crosslinked plasticderived therefrom preferably has dynamic shear moduli, over thetemperature range of 23° to 123° C., on or within the boundary of areaA-B-C-D of FIG. 1. Where the oligomers contain two or more "H" segments,such segments can be the same or different, as is true of the "S"segments and the "E" moieties. Further, the oligomers are free of labilegroups, viz., --O--O-- and --N═N--, and generally will have a numberaverage molecular weight of about 1000 to 30,000 grams per mole.

A class of such oligomers can be represented by the general formula##STR1## where "E", "H", and "S" are as broadly defined above, α is 1 or2, β is zero or an integer up to 20 whose average is less than about 5,and γ is 2 or 3.

"E" in formula I can be represented by the formula ##STR2## where R¹ isa hydrogen atom or methyl,

each A is independently --NH-- or --O--,

a, b, c and d are each independently zero or 1, with the provisos that

(1) at least one of b and d must be 1,

(2) if b and c are both zero, then a and d must be 1,

(3) if b and d are both 1, then a and c must be 1, and e is at least 2,and

(4) if d is 1 and a and b are both zero, then c must be 1,

e is an integer of 1 to 5,

subgenera of formula II being those of the formulas: ##STR3## wherepreferably R¹ is methyl and A is --O--, ##STR4## where preferably R¹ ismethyl, A is --O--, and e is 2, and ##STR5## where preferably R¹ is ahydrogen atom and A is --O--. "E" in formula I can also be thatrepresented by the formulas: ##STR6## where (in formulas II and IV) R²is hydrogen or a lower alkyl (e.g., with 1 to 4 carbon atoms andpreferably is methyl),

B is (CH₂)_(f;l) , --CO--, (CH₂)_(e) CO-- or (CH₂)_(f) OC(O)(CH₂)_(f)C(O)O(CH₂)_(f),

and each f is an integer of 2 to 5, each d is independenty zero or 1,and e is 1 to 5.

"H" in formula i can be represented by the formulas: ##STR7## or, where"E" in formula I is selected from the group of structures represented byformulas IIA, IIB, and IIC, "H" can be represented by the followingstructure: ##STR8## where (in formulas V, VI, VII, VIII and IX), each R²is independently as defined above for formula IV,

each R³ is independently a di-valent carbocyclic-containing radicalderived from benzene, naphthalene, cyclohexane, dicyclohexylmethane,diphenylmethane, or norbornene, and their lower alkyl-substitutedderivatives, by removal of two of their hydrogen atoms,

each R⁴ is independently an alkylene moiety with 2 to 10 (and preferably2, 4 or 6) carbon atoms, or a cycloalkylene moiety with 6 to 10 carbonatoms (and preferbly 8 carbon atoms, 6 of which are ring-carbon atoms),

each R⁵ is independently a phenyl moiety or (preferably) methyl

each R⁶ is independently a lower alkyl with 1 to 4 carbon atoms,preferably methyl,

g is zero or a number up to 5 (and preferably an average of 1 to 3),

B is as defined in formula IV,

h is an integer of 1 to 10,

h' is zero or an integer of 1 to 10, each d, d' and d" is independentlyzero or 1, with the proviso that if either one of d' or d" is 1, thenthe other is zero, and

A is as defined above for formula II.

"S" in formula I is a polysiloxane residue remaining after removal ofthe active hydrogen atom of polyols (illustrated by the generic formulaR_(s) (OH).sub.γ hereinafter) such as polysiloxane polyols, orpolysiloxane polyamines (illustrated by the generic formula R_(s)(NH₂).sub.γ hereinafter).

"S" in formula I can be a said polysiloxane residue represented by theformulas: ##STR9## where b' is a number of 6 to 35, and R is a linear orbranched alkylene group having 1 to 12 carbon atoms or a polyoxyalkylenegroup having 4 to 80 carbon atoms and 1 to 40 oxygen atoms, ##STR10##where the groups enclosed by the single brackets with subscripts b' andc' are repeating units randomly distributed within the double bracket,b' being a number of 6 to 35 and c' being 2 or 3, and R is as definedabove for formula XV.

Representative species of oligomers useful in making the shaped articlesof this invention and falling within the scope of formula I includethose having the structures represented in Table I.

    TABLE I      Formula    No. "E" "H" "S"           XXI      ##STR11##      ##STR12##      ##STR13##      XXII "     ##STR14##      ##STR15##      XXIV "     ##STR16##      ##STR17##      XXVII "     ##STR18##      ##STR19##      XXXII "     ##STR20##      ##STR21##      ##STR22##      XXXIII "     ##STR23##      ##STR24##       XXXVII CH.sub.2CHCOOC.sub.3 H.sub.6      O     ##STR25##      ##STR26##      XLV     ##STR27##      ##STR28##      ##STR29##       XLVII CH.sub.2CHCH.sub.2      O     ##STR30##      ##STR31##

Another class of oligomers useful in making the shaped articles of thisinvention can be represented by the general formula: ##STR32## where"E", "H", "S", α, β and γ are as defined for formula I. Sincerepresentative species of formula LV can be made with the same "E", "H"and "S" moieties as those species of formula I listed in TABLE I (thoughthe number and ratio of such moieties in the species of formula LV canbe different than the number and ratio of such moieties in the speciesof TABLE I), we will omit, in the interest of brevity, a similar list ofrepresentative species of formula LV.

Other classes of oligomers useful in making the shaped articles of thisinvention can be represented by the general formulas: ##STR33## where"H", "S", α, β and γ are as defined for formula I, but "E" in formulasLVI and VLII is represented by the formulas: ##STR34## where R¹ ishydrogen or methyl,

each A' and A" is independently --NH-- or --O--,

f is an integer of 2 to 5, and

each of b, c, d' and d" are independently zero or 1, with the provisosthat (1) if b and c are both zero then d' and d" are both zero (in whichcase R¹ is preferably hydrogen), or (2) if b and c are both 1, then d'and d" are both zero (in which case preferably R¹ is hydrogen, A' is--O--, and f is 2 or 3) or are both 1 (in which case preferably R¹ ismethyl and f is 2), ##STR35## where R¹ is hydrogen, or preferably,methyl, ##STR36## and where

R¹ is methyl or, preferably, hydrogen,

A is --NH-- or, preferably, --O--,

e is an integer of 1 to 5, preferably 1, and

d' and d" are either both zero (in which case R¹ is preferably hydrogenand e is 1) or both are 1, (in which case preferably R¹ is hydrogen, Ais --NH-- and e is 1).

Representative species of oligomers of formula LVI useful in making theshaped articles of this invention are set forth in TABLE II, wherestructural formulas for the various "E", "H" and "S" moieties of saidspecies have been omitted in the interest of brevity, reference insteadbeing made to structural formulas for said moieties which are set outhereinbefore. Representative species of oligomers of formula LVII can bemade with the same "E", "H", and "S" moieties as those species offormula LVI listed in Table II (though the number and ratio of suchmoieties in the species of formula LVII can be different than the numberand ratio of such moieties in the species of TABLE II); thus, we willomit, in the interest of brevity, a similar list of representativespecies of formula LVII.

                  TABLE II                                                        ______________________________________                                        Formula                                                                       No.     "E"              "S"     "H"                                          ______________________________________                                        LXIV    formula LVIII where                                                                            XXI     XXVIII*                                              b, c, d' and d" are                                                           1 and f is 2, R.sup.1 is                                                      CH.sub.3, A' is Oand                                                          A" is NH                                                              LXV     formula LVIII where                                                                            XXII    XXXVI**                                              b, c, d' and d" are                                                           1 and f is 2, R.sup.1 is                                                      CH.sub.3, A' is Oand                                                          A" is NH                                                              LXVII   formula LVIII where                                                                            XXII    XXVIII*                                              b, c, d' and d" are                                                           1 and f is 2, R.sup.1 is                                                      CH.sub.3, A' is Oand                                                          A" is NH                                                              LXXII   formula LIX where R.sup.1                                                                      XXII    XXI                                                  is CH.sub.3                                                           LXXV    formula LIX where R.sup.1                                                                      XXI     XXXVI**                                              is CH.sub.3                                                           LXXVIII formula LX where R.sup.1                                                                       XXII    XXXVI**                                              is H, A is NH, and                                                            d', d" and e are 1                                                    LXXIX   formula LX where R.sup.1                                                                       XXII    L*** and XXI                                         is H, A is NH, and                                                            d', d" and e are 1                                                    ______________________________________                                         ##STR37##                                                                     ##STR38##                                                                     ##STR39##                                                                

The radiation addition-polymerizable, crosslinkable oligomericcomposition useful in making the shaped articles of this invention canbe prepared by general reactions that are well-known in the art ofpreparing addition polymerizable materials. Those general reactions aretypically of two types: (1) addition reactios, viz., the urethane- orurea-forming reaction between an active hydrogen organic compound andisocyanate or the ether-forming reaction between an active hydrogenorganic compound and and epoxy compound, and (2) condensation reactions,viz., esterification or etherification of an active hydrogen organiccompound with a carboxylic acid or ester or acylhalide derivativethereof or with an alkyl ether, accompanied by elimination of abyproduct; for the preparation of some oligomeric compositions, bothtypes of reactions will be employed as shown hereinafter. Such reactionsare commonly used in synthetic polymer chemistry, e.g. see Saunders, J.H. and K. C. Frisch, "Polyurethanes: Chemistry and Technology", Part 1(1962), especially Chapter III; Lee, H. and K. Neville, "Handbook ofEpoxy Resins" (1967), especially Appendix 51; Bruins, P. F. "Epoxy ResinTechnology" (1968), especially Chapters 1 and 2; Kirk-Othmer"Encyclopedia of Chemical Technology" 2nd Ed., Vol. 8, p. 313 (1965);Roberts, J. D. and M. C. Caserio, "Basic Principals of OrganicChemistry", p. 518 (1964). These general reactions are thus used tochemically combine "E" moieties with the "H" and "S" segments to formoligomeric compositions of use in the invention. Generally, thecombining of the "E", "H" and "S" moieties is carried out in a sequenceof steps; however, under some circumstances, it is convenient to carryout the reactions simultaneously and even to form the oligomericcomposition in situ during the process of making the replicated plasticarticles of this invention, e.g., carrying out the ether-formingaddition reaction in situ in the replication mold.

Generally, the urethane- or urea-forming reactions are carried out attemperaftures from 25° to 100° C. for 10 minutes to several hours ormore, sufficient to bring about the reaction. Preferably, a catalystsuch as dibutyltin dilaurate is used to promote the reaction.Generalized equations for such reactions in preparing the oligomericcomposition used in this invention are illustrated as follows where theprecursors of "H", "S" and "E" are denoted by formulas containing suchletters as subscripts, the formula containing C as a subscript being achain extending compound, and g, β and γ are as defined for formula I:##STR40##

The ether-forming addition reactions are carried out generally attemperatures of 75° to 150° C. (or ambient temperatures when carried outin situ in the replication of the plastic articles), preferably in thepresence of catalysts such as Lewis acids, e.g., BF₃.O(C₂ H₅)₂, or Lewisbases, e.g., benzyltrimethylammonium hydroxide, or photoactivecatalysts, such as the aryl iodonium or sulfonium salts described inU.S. Pat. No. 4,081,276, when the reaction is carried out in situ.Generalized equations for such reactions in preparing the oligomercomposition are illustrated as follows: ##STR41##

Representative ether-forming condensation reactions are those between"E" and "S" precursors having active hydrogens with an N-(loweralkoxymethyl) melamine as an "H" precursor, as illustrated by thefollowing equations: ##STR42## The reactions are promoted with acidcatalyst such as p-toluene-sulfonic acid. Generally, temperatures from60° to 120° C. for one to three hours or more can be used. The use ofreduced pressures to remove volatile lower alkanol is alsso desirable.

Esterification reactions are illustrated by the following equations:##STR43## Such esterification reactions require the elimination of abyproduct (water, hydrogen halide, or lower alcohol). Esterificationsare promoted by heating the mixture at 50° C. to 150° C. in the presenceof a suitable catalyst, e.g., toluenesulfonic acid. The use of reducedpressures to remove volatile byproduct is also desirable.

Physical propertires, e.g., thermal dimensional stability, of thecrosslinked polymer resulting upon curing of said oligomeric compositionwill be dependent on the crosslink density of the polymer. An indicationof that crosslink densiity can be derived by calculating the molecularweight per crosslink based on the monomeric precursor components of theoligomeric compositionl. That calculation, for example, in the case ofExample 1, infra, is made by subtracting the gram moles of the "S"precursor from the gram moles of the "H" precursor, and dividing thedifference into the total weight in grams of the monomeric precursorcomponents in the oligomeric composition, the so-calculated molecularweight per crosslink being 1241. Generally, the calculated molecularweight per crosslink for the polymers will be in the range of 400 to5000, preferably 1000 to 3000 the actual value generally being somewhathigher because of side reactions, incomplete reactions, etc.

The oligomeric products resulting from the aboveillustrated equations(1) to (13) have predominantly the structures shown. The oligomericproduct of equations (1), (2), (5), (7), (9), and (11) are encompassedby generic formula I; those of equations (3), (4), (10), and (12) byformula LVI; those of equations (6) and (8) by formula LV; and that ofequation (13) by formula LVII. For example, in the oligomeric product ofequation (1), R_(E) O--, --CONH--R_(H) --NHCO--, and --O--R_(S) --O--correspond respectively to "E", "H", and "S" of formula I where α is 1.And in the oligomeric product of equation (2), which also falls withinthe scope of formula I where α is also 1, R_(E) O-- corresponds to--E--, --CONH--R_(H) --NHCO(O--R_(C) OCONH--R_(H) --NHCO)_(g)corresponds to the "H" bonded to "E", the --CONH--R_(H) --NHCO-- moietybonded to --OR_(S) O-- corresponds to the "H" bonded to "S", and--OR_(S) O-- corresponds to "S".

The oligomer products produced by these reactions often will be highlyviscous and thus difficult to cast in the replication mold, and inaddition may not be capable of producing the necessary crosslinksdensity in the subsequently cured plastic article. Thus, it may benecessary to add to the oligomer product a radiationaddition-polymerizable mono- or polyfunctional diluent monomer, e.g.,2-(N-butylcarbamyl) ethylmethacrylate, to lower the viscosity of thecasting oligomeric composition and ensure the necessary crosslinkdensity in the plastic article made therefrom, that crosslink densitybeing manifested in a gel swell (determined in tetrahydrofuran, ashereinafter described) within the range of 35 to 200 wt. %, preferably80 to 150 wt. %. Generally the amount of diluent monomer used should beless than 50 wt. % of the oligomeric composition (viz., oligomers plusdiluent monomer), since greater amounts will reduce the concentration ofthe "H" and "S" segments below that required to provide the desiredreplicated plastic articles of this invention and will further increasethe shrinkage during curing.

The oligomeric compositions (including the diluent monomer where used)and the articles made therefrom have the same amount of "H" segments andthe same amount of "S" segments (and consequently the same ratio ofthese moieties). Said amount of "H" generally will be an amount in therange of 10 to 80 wt. % (of which amount at least 30 wt. % is due to thecarbocyclic and heterocyclic groups), "H" preferably being 15 to 60 wt.%, and said amount of "S" will be an amount in the range of 10 to 60 wt.%, preferably 15 to 45 wt. %, the balance in the oligomeric compositionbeing that attributable to the functional moieties "E" and the diluentmonomer from which linking segments or moieties are derived as thebalance of the plastic articles. Those plastic articles preferably havemoduli over the temperature range of 23° to 120° C. which fall on orwithin the boundar A-B-C-D of FIG. 1, which property is measured by theprocedure described in U.S. Pat. No. 3,853,595 where it is referred toas "storage shear modulus, G'". The particular amounts of "H", "S" and"E" in the oligomeric composition are such that the crosslinked polymerderived therefrom preferably has such moduli. Said moduli are dependenton the "H" and "S" contents and the crosslink density of the plastic,said crosslink density being manifested in gel swell as mentioned above.If a particular oligomer composition has "H", "S" and "E" contentsfalling within their said ranges and yet the crosslinked polymer derivedtherefrom has a dynamic shear moduli curve which falls in whole or inpart above the line A-B of FIG. 1, indicative of a plastic which may betoo rigid for a particular article of this invention, the "H" content ofthe oligomeric composition will have to be lowered, e.g., by employing ahigher molecular weight "S" precudrsor or by eliminating or decreasingthe amount of chain extender in the preparation of the oligomericcomposition, or the crosslink density will have to be lowered by using ahigher molecular weight "H" precursor or higher molcular weight "S"precursor. On the other hand, if the dynamic shear moduli falls in wholeor part below the line D--C of FIG. 1, indicative of a plastic which maybe too flexible for a particular article of this invention, the "H"content of the oligomeric composition will have to be increased, e.g.,by using a lower molecular weight "S" precursor and/or employing a chainextender together with additional "H" precursor, or the crosslinkdensity will have to be increased by using a lower molecular wt. "H"precursor or "S" precursor or by employing a multifunctional diluentmonomer, e.g., 1,6-hexanediol diacrylate. The proper particular amountsof "H" and "S" and crosslink density for a particular system necessaryto provide the preferred dynamic shear moduli defined by A-B-C-D of FIG.1 can be readily arrived at empirically by varying the above parametersas discussed above. These adjustments of dynamic moduli are based on thegenerally linear relationship, on a logarithmic basis, between dynamicmodulus (or tensile strength) and the amount of "H" in the curedplastic.

The materials which can be used as "H", "S" and "E" precursors in makingthe oligomeric compositions used in this invention, as well as chainextending agents and catalysts used in their preparation and diluentmonomers and radiation or photo sensitizers and initiators incorporatedtherein, are known materials, many of which are commercially available.An illustrative description of those materials follows below, referencebeing made to patents and the literatured for purposes of brevity.

Polysiloxane polyols useful as "S" precursors include hydroxy-terminateddiorgano-polysiloxanes in U.S. Pat. Nos. 4,098,742 and 3,886,865, andthe siloxanes having a reactive hydroxyl group bonded to at least 2 ofits silicon atmos, described in U.S. Pat. Nos. 3,577,264, 3,976,676, and4,013,698.

Particularly useful, commercially available "S" percursors are siliconepolycarbinols sold under the trademark "DOW CORNING", such as Q4-3667.

Polyisocyanates, especially diisocyanates, which can be used as "H"precursors, include those described in U.S. Pat. Nos. 3,641,199;3,700,643; 3,819,586; 3,878,036; 3,931,117; 3,960,572; and 4,065,587.Epoxides which can be used as "H" precursors include diglycidyl ethersof bisphenol A, diglycidyl isophthalate, diglycidyl phthalate,o-glycidyl phenyl glycidyl ether, diglycidyl ethers of resorcinol,triglycidyl ethers of phloroglycinol, triglycidyl ethers of methylphloroglycinol, diglycidyl phenyl ether and diglycidyl ether ofhydrogenated bisphenol A, all of which are described in Appendix 4-1 of"Handbook of Epoxy Resins", by H. Lee and K. Neville, McGraw-Hill BookCompany (1967).

Particularly useful commercially available diisocyanates which can beused as "H" precursors include isophorone diisocyanate sold under thetrademark "IPDI" by Veba-Chemie AG and methylenebis(4-cyclohexylisocyanate) sold under the trademark "Hylene" WS byDuPont.

"E" precursors which can be used include the acrylyl compounds describedin U.S. Pat. No. 3,700,643, the hydroxy acrylates and methacrylatesdescribed in U.S. Pat. No. 3,577,262 the ethylenically-unsaturatedalcohols described in U.S. Pat. No. 3,297,745, the hydroxyalkylacrylatesand methacrylates described in U.S. Pat. No. 4,065,587, theethylenically unsaturated alcohols described in U.S. Pat. No. 3,960,572and the following epoxides: butyl glycidyl ether, diglycidyl ether ofpropylene glycol, diglycidyl ether of butanediol, vinylcycohexenedioxide, mixed isomers of bis (2,3-epoxycyclopentyl)ether,bis(3,4-epoxy-6-methylcyclohexylmethyl) adipate,bis(3,4-epoxycyclopentyl)ether, 3,4-epoxy-6-methylcyclohexanecarboxylate, para-butylphenol glycidyl ether, limonene dioxide,dicyclopentadiene dioxide and 3,4epoxy-t-methylcyclohexylmelthyl-4-epoxy-6-methylcyclohexane carboxylate,all of which epoxides are described by Lee and Nevill, supra.

Chain extenders which can be used in preparing the oligomers used inthis invention include the known hydroxy-, carboxy-, amino ormercapto-terminated compounds useful for that purpose (see U.S. Pat. No.3,448,171.)

To promote oligomer-forming reactions, it is generally desirable toutilize a catalyst. Typical examples of such catalysts include compoundscontaining tertiary amino groups, tin compounds and titanium compounds.

Examples of the preferred tin compounds are dibutyltin dilaurate,dibutylin diethylhexoate, dibutyltin sulfide, dibutyltin dibutoxide,stannous octoate, stannous oleated and stannous chloride. Concentrationsof catalyst from about 0.01 to about 0.5 percent and preferably about0.025 to 0.1 percent by weight of the total weight of reactants(exclusive of solvents) can be used.

The diluting monomers are addition-polymerizable monomers, viz.,ethylenically unsaturated monomers and vicepoxy reactive diluenfts. Thediluting monomers contribute to the "H", "S" or "E" content of theoligomeric composition depending on the glass transition temperature,T_(g), of a homopolymer of the particular monomer. If the T_(g) of itshomopolymer is above about 350° K., the monomer contributes to the "H"content, below about 250° K. to the "S" content, and between about 250°K. and 350° C. to the "E" content. The concept of "hard" and "soft"monomers is well known (e.g., U.S. Pat. Nos. 4.077,926 and 4,077,932)and has been used to describe monomers to be optionally used in adhesivecompositions.

Suitable ethylenically unsaturated diluting monomers and the glasstransition temperature of their homopolymers are well known in polymerchemistry literature, e.g., Brandrup and Immergut, Polymer Handbook,III--61 to 73, Interscience Publishers (1967). Examples of the "hard"monomers (and the T_(g) of their homopolymers) are isobornyl acrylate(367° K.), melthyl methacrylate (378° K.), cyclohexylchloroacrylate(372° K.), 2-chlorostyrene (392° K.), 2,4-dichlorostyrene (406° K.),styrene (373° K.), acrylic acid (360° K.) acrylamide, acrylonitile (393°K.) and methacrylonitrile (393° K.). Examples of the "soft" monomers(and the T_(g) of their homopolymers) are butyl acrylate (218° K.),ethyl acrylate (249° K.), 2-ethylhexyl acrylate (223° K.), dodecylmethacrylate (208° K.), and 4-decylstyrene (208° K.). Examples ofdiluting monomers which contribute to neither the "hard" content nor tothe "soft" content but become incorporated into the linking segments(and the T_(g) of their homopolymers) are 4-cyclohexyl-1-butene (318°K.), 1-dodecan (267° K.), t-butyl acrylate (251° K.), cyclohexylacrylate dodecyl acrylate (270° K.), isopropyl acrylate (270° K.),methyl acrylate (279° K.), butyl methacrylate (293° K.), 4-butoxystyrene(320° K.), 2-(N-butylcarbamyl)ethyl methacrylate (304° K.) and2-(N-ethylcarbamyl)ethyl methacrylate. Polyethylenically unsaturatedmonomers also become incorporated into the linking segments and are usedin small quantities to reduce the molecular weight of the curedoligomeric composition per crosslink. Typical of such compounds are1,4-butylene dimethacrylate or acrylate, ethylene dimethacrylate oracrylate, trimethylolpropane di- or tri-acrylate, glyceryl diacrylate ormethacrylate, glyceryl triacrylate or methacylate glycidyl acrylate ormethacrylate, pentaerythritol triacrylate or trimethacrylate, diallylphthalate, 2,2-bis(4-methacryloxyphenyl)-propane, diallyl adipatedi(2-acryloxyethyl)ether, dipentaerythritol pentaacrylate,neopentrylglycol triacrylate, polypropylene glycol diacrylate ordimethacrylate, and 1,3,5-tri-(2-methacryloxyethyl)-s-triazine.

Diluting epoxy-reactive monomers include phenyl glycidyl ether,4-vinylcyclohexene dioxide, limonene dioxide, 4-vinyl-cyclohexene oxide,1,2-cyclohexene oxide, glycidyl acrylate, glycidyl methacrylate, andstyrene oxide.

Suitable addition-polymerization catalysts for use in the oligomericcompositions wherein the addition-polymerizable group is anethylenically unsaturated group as represented in formula II, viz.,acrylic or olefinic, are catalysts which liberate or generate afree-radical on addition of energy. Such catalysts are well known andare described frequently in polymerization art, e.g., Chapter II of"Photochemistry" by Calvert and Pitts, John Wiley & Sons (1966).Included among free-radical catalysts are the conventional heatactivated catalysts such as organic peroxides and organichydroperoxides; examples are benzoyl peroxide, tertiary-butylperbenzoate, cumene hydroperoxide, azobis (isobutyronitrile) and thelike. The preferred catalysts are photopolymerization initiators which,when used in an addition-polymerizable group-containing composition,facilitate polymerization when the composition is irradiated. Includedamong such initiators are acyloin and derivatives thereof, such asbenzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropylether, benzoin isobutyl ether, and α-methylbenzoin; diketones such asbenzil l and diacetyl, etc.; organic sulfides such as diphenylmonosulfide, diphenyl disulfide, decyl phenyl sulfide, andtetramethylthiuram monosulfide; S-acyl dithocarbamates, such asS-benzoyl-N,N-dimethyldithiocarbamate; phenones such as acetophenone, α,α, α-tribromoacetophenone, α, α-diethoxyacetophenone, o-nitro-α, α,α-tribromoacetophenone, benzophenone, andp,p'-tetramethyldiaminobenzophenone; sulfonyl halides such asp-toluenesulfonyl chloride, 1-naphthalenesulfonyl chloride,2-naphthalenesulfonyl choride, 1,3-benzenedisulfonyl chloride,2,4-dinitrobenzenesulfonyl bromide and p-acetamidobenzenesulfonylchloride. Normally, the initiaor is used in amounts ranging from about0.01 to 5% by weight of the total oligomeric composition. When thequantity is less than 0.01% by weight, the photopolymerization ratebecomes extremely low. If the initiator is used in excess of 5% byweight, no correspondingly improved effect can be expected. Thus,addition of such greater quantity is economically unjustified.Preferably, about 0.25 to 1.0% of initiator is used in the oligomericcompositions.

For those oligomeric compositions in which the radiation sensitiveaddition-polymerizable, functional group-containing moiety is an epoxygroup as represented in formulas III or IV, any catalyst can be usedwhich liberates or generates a cationic polymerization catalyst uponexposure to radiation. These catalysts are onium salts that are wellknown in the art of polymerization, e.g., U.S. Pat. No. 3,826,650 inwhich it is taught that photosensitive latent curing agents classifiedas aromatic diazonium salts of a complex anion, e.g.,hexafluoroantimonate, and the like are used for photopolymerizing epoxymonomers, and U.S.Pat. No. 4,081,276 in which it is taught thatphotoinitiators capable of releasing a cationic polymerization catalystupon exposure to radiant energy are aromatic halonium, aromatic Group Vaonium, and aromatic Group VIa onium salts of complex anions and aresuitable for forming an image on a substrate. The preferred catalyst forpolymerizing the oligomeric compositions of the invention in which theaddition-polymerizable functional group-containing moiety is an epoxygroup are aromatic iodonium or sulfonium salts of complex anionsselected from tetrafluoroborate, hexafluorophospate,hexachloroantiomonate, and hexafluoroantimonate. Examples of such saltsinclude diphenyliodonium hexafluorophosphate, diphenyliodiniumhexafluoroantimonate, triphenylsulfonium hexafluorophosphate, andtriphenyl hexafluoroantimonate. Other preferred aromatic onium saltphotoinitiators are the aromatic iodonium and sulfonium salts offluoroaliphatic sulfonic acid and thebis(fluoroaliphaticsulfonyl)methanes that are disclosed in U.S. Pat. No.4,049,861.

In making a particular shaped plastic article of this invention for aspecific application, economic considerations will influence whatparticular oligomeric composition or compositions and which mode ofpreparation thereof should be used for that purpose. For example, inmaking retroreflective cube corner sheeting for use as highway trafficcontrol markers where such requirements as resistance to weathering andhigh impact strength are essential, urethane-containing oligomericcompositions preferably would be selected, such as those within thescope of formulas I or LV, the urethane linkage imparting stability tothe sheeting upon its exposure to light, heat and moisture, and the modeselected for making such oligomeric composition advantageously beingthat of aforesaid equation (2) because, for example, it involves onlytwo reaction steps and results in an oligomeric product with arelatively high content of "H" segments, necessary for satisfying thehigh impact strength requirement of the sheeting, and because equation(2) permits the use of hydroxyacrylates, such as2-hydroxyethylmethacrylate, and cycloaliphatic polyisocyanates, such asisophorone diisocyanate, these types of reactants being commerciallyavailable raw materials which will augment that of the urethane linkagein providing the desired degree of weatherability.

As another example, in making flexible video discs, where high abrasionresistance and optical transparency are important, urethane-containingoligomeric composition preferably would be selected, such as thosefalling within the scope of formulas I or LV, the urethane linkageimparting abrasion resistance to the disc, and the mode selected formaking such oligomeric composition advantageously being that ofaforesaid equation (1) because, for example, of its limited number ofreactions and its amenability to use of reactants which are commerciallyavailable and which impart to the disc requisite flexibility, highoptical transparency, and low haze; such reactants are cycloaliphaticpolyisocyanates, such as isophorone diisocyanate, which also arecommercially available and which also impart to the oligomericcomposition the property of fast radition curability.

As still another example, in making Fresnel lenses where high opticaltransparency is important for image projection and high focusingefficiency is important for solar heat concentration,urethane-containing or aromatic carbonate-containing oligomericcompositions preferably would be selected, such as those within thescope of formulas I or LV, the urethane linkage imparting stability tolight and heat and the aromatic carbonate moiety imparting highrefractive index and concomittant low chromatic aberration, and the modeselected for making said urethane-containing oligomeric compositionsadvantageously being that of equations (1) and (2) and the mode formaking said carbonate-containing oligomeric compositions advantageouslybeing the aforesaid equations (9) or (10), said equations (1), (2), (9)and (10) entailing a limited number of reactions and being amenable touse of commercially available materials as reactants for imparting therequisite properties to the plastic articles. In the case of projectionlenses and solar collectors, said reactants can be isophoronediisocyanate, polycaprolactone polyols, and hydroxyacrylates.

The shaped plastic articles of this invention are typically prepared bypouring or filling a mold master with the oligomeric composition,exposing the resulting cast composition to actinic radiation to rapidlycure the same, and removing from said mold master the resulting shapedplastic article which comprises crosslinked plastic and has a surfacebearing microstructure replicated from the mold master.

The particular mold master used in replication will depend on the typeof shaped article to be made. For purposes of making optical lenses,e.g., ophthalmic lens blanks, having a surface with an optical finish,the mold master can be made of transparent (e.g., "Pyrex") glass, suchmasters being commercially available. For purposes of making diffractiongratings, e.g., spectral filters, light collectors, and decoratingdecals, the mold master can be made of metal with the diffractionpattern thereon made by mechanical ruling or holographically, suchdiffraction grating masters being commercially available, e.g., see the"Diffraction Grating Catalog" (1974), of PTR Optics Corp., Waltham,Mass., and Bulletins ACA 1004-1-1270 and ACA 1006-1-1-270 of AngenieuxCorp. of America, Oceanside, N.Y.

For cube-corner sheeting, linear Fresnel lenses, and other shapedplastic articls having raised or indented microstructure-bearingsurfaces, mold masters can be used which are made of plastic, e.g.,acrlonitrile-butadienestyrene, or preferably (for mass production ofsuch replicated articles) made of metal fabricated directly from asuitable metal by engraving, hobbing, assembling as a bundle a pluralityof metal parts machined in the desired configuration, or othermechanical means or by electroforming, e.g., see "Encyclopedia ofPolymer Science & Technology", Vol. 8, p. 651 (1968), and "Principles ofElectroplating and Electroforming", W. Blum and G. B. Hogaboom, 3rd Ed.McGraw-Hill Co., Inc., Chap. VIII (1949), and U.S. Pat. No. 3,689,346.

Where the microstructure to be replicated can be initially formed bymachining originals made of plastics which are difficult to wet, such ascommercially available acrylic resins, e.g, that sold under thetrademark "LUCITE", electroformed metal mold masters can be formed fromsuch machined originals and used to make shaped plastic articles (suchas the diffraction gratings, Fresnel lenses and retroreflective sheetingdescribed in the working examples of this specification) by treating themachined plastic surface to render it wettable and sensitized (forexample, by the treatment described in U.S. Pat. No. 3,666,527),rendering the surface conductive by simultaneous contact, using atwo-nozzle spray gun, with an ammonical silver salt solution, and areducing agent, such as formaldehyde or dextrose, plating orelectroforming nickel on the silver-coated surface from a commerciallyavailable nickel bath, and separating the resulting metal layer from theplastic original, thus generating a metal master which can be used forreplicating said shaped plastic articles or from which second and thirdgeneration electroformed nickel copies can be made as required toprovide a tooling supply for replicating said shaped plastic articles.Where the microstructure to be replicated can not be initially machinedon a plastic original for purposes of making masters used in replicatingsuch articles as the video disc described hereinafter in a workingexample of this specification, mold masters fabricated by photoresisttechniques can be used, e.g., see the journal articles in "Science",Vol. 196, No. 4293, p. 945 (1977), and "Optics and Laser Technology"August, 1977, p. 169.

The cast, curable oligomeric composition can be cured by exposure toactinic radiation, viz., ionizing or non-ionizing radiation, a curingtechnique well-known and widely-used in the art of radiation additionpolymerization (e.g., see U.S. Pat. No. 3,700,643). Typically,ultraviolet radiation produced by such sources as mercury arcs,sunlamps, or xenon lamps, with UV radiation primarily in the regions ofabout 2000 to 4000 A, will be most useful. Ionizing radiations producedby electron accelerators, e.g., continuous filament or swept beamaccelerators, can be used, wherein the electrons are provided with thekinetic energy derived from acceleration through a field varying from150 kilovolts up to as high as 4000 kilovolts. Useful radiation dosagerequired to complete the curing will vary, depending on the particularoligomeric composition used, its molecular weight and the crosslinkingdensity desired; for ultraviolet radiation, a useful dosage willgenerally be in the range of 0.1 to 100 joules per square centimeterexposed and for ionizing radiation, such as electron beam, a usefuldosage will be 5×10³ rads to 10⁷ rads. Normally the exposure is carriedout a or near room temperature and atmospheric pressue. An inertatmosphere, such as nitrogen or carbon dioxide gases, may be desired incuring some oligomeric compositions, viz., those relying on free-radicalcuring mechanisms, e.g., acrylate-, or methacrylate-terminatedoligomers. Radiation processing equipment useful in the practice of thisinvention is commercially available, e.g., ultraviolet lamp systems soldby Radiation Polymer Corp., Plainfield, Ill., and Fusion Systems Corp.,Greenbelt, Md., and ionizing radiation systems sold by Energy Sciences,Inc., Burlington, Mass, and Radiation Dynamics, Inc., Long Island, N.Y.(Although the radiation used in curing the oligomeric composition hasbeen described in detail herein as being actinic radiation, thermalradiation can be used, e.g., 50° to 150° C. for 5 min to several hoursdepending on the oligomeric composition and catalyst used; thermalradiation is not preferred because it is more time-consuming, requiresmore energy, and is not as controllable as actinic radiation).

Following radiation of the cast composition (actinic radiation effectscomplete curing in 1/2 to 5 seconds generally), the cured, shapedplastic article is readily separated or removed from the mold master.Mold release agents may be used, though generally they are not required.Depending on the particular shaped plastic article made and the natureof the mold master, the mold master can be repeatedly used forreplication done on a continuous mass production basis.

In selecting an oligomeric composition for use in preparing a particularshaped article, it has been found useful to prepare a transmissivediffraction grating test sample from the composition. Such sample can beused to measure replicating fidelity capability of the oligomericcomposition and the thermal dimensional stability capability of theoligomeric composition. FIG. 2 schematically illustrates a replicateddiffraction grating useful as a test sample, the preparation and testingof which is described hereinafter. The test measures the first orderdiffraction efficiency of both the master grating and replicated testsample, the efficiency of which is related to the depth of the grooves.A comparison of the efficiency of the replicated test sample to that ofthe master grating determines the fidelity of replictions. Generally theoligomeric composition of this invention will give diffraction gratingtest samples having a replicated efficiency of at least 85% of that ofthe master grating. For some particular shaped articles, the replictionefficiency must be significantly greater than 85% (for example, forreplicated video discs, the replication efficiency must approach atleast 99%) and for such articles an oligomeric composition must beselected which will produce a diffraction grating test sample havingsuch repliction efficiency. Replication efficiency will be dependent onthe degree of shrinkage of the diffraction grating test sample; thegreater the shrinkage, the lower the replication fidelity. Shrinkage inturn is dependent on the number of double bonds present in theoligomeric composition per unit weight thereof, and generally thegreater such number of double bonds, the greater the degree ofshrinkage. For acrylate- or methacrylate-terminated oligomers, theshrinkage will be about 20 cc/gram mole of double bonds, and thisshrinkage factor can be used as a guide in selecting an oligomericcomposition necessary to yield the desired replication efficiency.

Generally, the oligomeric compositions will yield diffraction gratingtest samples which have high thermal dimentional stability. For example,generally when said test samples are heated in air in a programmedmanner from 23° to 170° C., the first order diffraction efficiency ispractically constant over these temperatures. (By contrast, the firstorder diffraction efficiency of comparative diffraction grating testsamples made of poly(methy methacrylate), polyvinyl chloroide, celluloseacetate butyrate, and polyethylene terephthalate dropped rapidly orprecipitously to zero when the temperature reached about 70° to 115°C.). The change in first order diffraction efficiency of diffractiongrating test samples of the oligomeric compositions of this inventionupon heating at 130° C. in air for 1 hour is less than 15%, as comparedto the first order diffraction efficiency before heating. Generally, thehigher the weight ratio of "H" to "S" in the oligomeric composition, andthe lower the molecular weight between crosslinks in the shaped articleproduced therefrom, the greater the thermal dimensional stability, i.e.,the smaller the change in first order diffraction efficiency uponheating.

Some of the shaped articles of this invention will require higherthermal dimensional stability than others, viz., a change in first orderdiffraction efficiency on heating at 130° of less than 5%. For example,replicated cube-corner sheeting, the use of which exposes it to elevatedtemperatures, e.g., on a road sign heated by the sun in Arizona, willrequire a high thermal dimensional stability, whereas a replicted videodisc, played at room temperature, will not require high thermaldimensional stability.

In addition to the preparation of diffraction grating test samples, ithas been found useful to prepare cured, self-supporting film samples(with planar surfaces) of the oligomeric composition and measure thetensile strength, elastic modulus, elongation-to-break, and dynamicshear moduli of the film samples, the preparation and testing of whichis described elsewhere herein. The values of these measurements will befactors to consider in selecting an oligomer composition for fabricationof a particular shaped plastic article therefrom. For example, areplicated video disc which may have to be relatively limp (or "floppy")for playing on a particular type of player, would be prepared fromoligomeric compositions which yield test film samples having relativelylow elastic modulus and dynamic shear moduli and relatively highelongation. In contrast, a rigid or stiff repliated Fresnel lens, usedfor projection of images, would be prepared from oligomeric compositionswhich yield test film samples having relatively high elastic modulus anddynamic shear moduli, and relatively low elongation. The test filmsamples can also be measured for optical properties as an aid inselection of an oligomeric composition for preparation of replicatedshaped plastic articles used for optical purposes, e.g., where it isnecessary to satisfy requirements of high transmission (i.e., at least90%) and low haze (i.e., less than 5%, preferably less than 2%).

FIGS. 3 and 4 schematically illustrate a portion of a typical replicatedcube-corner retroreflective sheet 1 made in accordance with thisinvention. The geometry or configuration of this type of article isdescribed, for example, in U.S. Pat. No. 3,810,804. Reference 2generally designates one of the minute cube corner elements orformations disposed in an array on one side of the sheeting 1. Eachelement 2 has the shape of a trihedral prism with three exposed planarfaces, substantially perpendicular to one another, with the apex of theprism vertically aligned with the center of the base. The angle betweenthe faces is the same for each cube-corner element in the array, andwill be about 90°. Said angle can slightly deviate from 90° by design,i.e., the angle will be dependent upon the particular application of thesheeting, as is well-known. For example, in the United States, stategovernments generally specify maximum brightness of retroreflectivetraffic control markers at from 0.2° to 2° divergence (or observational)angles, thus dictating a specific angle between the faces of thecube-corner elements in the marker. The cube corner elements 2 in sheet1 are all of the same dimensions and are aligned in an array or patternof rows and columns, the bases being in the same plane, and adjacentelements being contiguous at the edges of their bases such that there isnot spacing or flat areas between adjacent elements. The cube-cornerelements 2 surmount a body portion 3, the lower surface of which issmooth or planar, the body portion being preferably integral withelements, the sheeting thus being monolithic. Generally, eachcube-corner element 2 has a side edge dimension up to 0.025 inch (0.635mm), preferably less than 0.010 inch (0.254 mm). The body portion 3 issufficiently thick to render the sheeting self-supporting and tough soas to maintain the integrity of the array of cube-corner elements 2.Generally, the body portion will be 0.002 to 0.030 inch (0.05 to 0.075mm), preferably 0.003 to 0.010 inch (0.075 to 0.25 mm).

In the application of such cube-corner sheeting as a highway trafficcontrol marker, it will be desirable to seal air spaces between thefaces of the cube-corner elements with a sealing film placed over thetop of the elements, e.g., in the manner described in U.S. Pat. No.4,025,159, and coat the exposed surface of the film with apressure-sensitive adhesive composition which is dried and adhered to arigid sheet, e.g., aluminum, which forms a base for the resultingmarker. The exposed lower surface 8 of the body portion 3 of thecube-corner sheeting 1 may be first selectively coated with transparentink layers to provide the desired traffic control message, e.g., "STOP",and then coated with a top coat to protect the message, e.g., againstweathering.

The principle of operation of retroreflective cube corner structures iswell known, e.g., see J. Optical Society of America, Vol. 48, No. 7,July, 1958, p. 496. That principle is in essence illustrated by FIG. 5.Referring to that figure, in which a single cube corner element 2 isshown schematically with two of its faces 6, 7 being substantiallyperpendicular to one another, as shown by the angle 90°±θ, and the bodyportion 3 having an exposed lower surface 8. An incident ray of light Ienters the element 2 upon striking surface 8 in a directionperpendicular thereto, passes through the body portion 3, strikes face6, is reflected to the other faces, is reflected from the latter andpasses out of the element as reflected ray I'. Perfect retroreflectionof incident ray I for the particular element shown in FIG. 5 wouldresult in the reflected ray passing out the element in a path, shown bythe broken line, exactly parallel to the path of the incident ray. Thedeviation between the path of perfect reflection and the actual path,I', is shown by the divergence angle δ, which will be 0.2° to 20° in thecase where state governments specify the same as described above. Inorder to obtain and maintain the desired specified divergence angles,the desired dimensions and angles of the cube-corner elements must beobtained and maintained within very narrow limits. For example, asdescribed by J. Optical Society of America, supra, for a plastic havingan index of refraction of 1.5 (typical for the plastics comprising theshaped articles of this invention, said plastics generally having anindex of 1.48 to 1.6), the divergence angle δ an be expressed by theequation δ=4.9 θ, and thus when δ is 0.2°, θ is 0.041° or 2.46 minutesof arc, which is an exceedingly small angle. If the angles between thefaces of a replicated cube-corner element cannot be controlled andmaintained, e.g., because of shrinkage, distortion upon removal from themold, or of thermal distortion, the efficiency of retroreflection willbe affected. Even a slight lack of control and maintenance of the anglecan significantly adversely affect the efficiency. Rigid, high elasticmodulus plastics, such as poly (methyl methacrylate), have thus beenresorted to in the art, however, such plastics are brittle and have lowheat distortion resistance. In contrast, the desired angles of theplatic cube corner elements made in accordance with this invention arecontrolled and maintained even at elevated temperatures, and theelements are flexible, articles with such elements being of wideapplication, e.g., where high impact strength is desired or required, asin the case of highway "STOP" signs. Additionally, the retroreflectivecube-corner sheeting of this invention can be made with initial highbrightness capability, e.g., at least 600 candles/lumen at 0.2°divergence angle.

FIG. 4A illustrates the combination of the replicated cube-cornerretroreflective sheet 1 of FIGS. 3, 4 with a retroreflective beadedsheet 14, this type of construction being described in U.S. Pat. No.4,025,159, as a combination cube-corner exposed-lens product of thegeneral type described in U.S. Pat. No. 3,140,340. Sheet 14 comprises alayer 15 of binder material, a monolayer of transparent glassmicrospheres 16 partially embedded in the binder material, and specularreflective material 17 underlying and in optical connection with theembedded surface of the microspheres. The points of contact between theapices of cube-corner elements 2 and microspheres 16 can be bonded asshown in FIG. 4A and as taught in U.S. Pat. No. 4,025,159, forminghermetically sealed cells or pockets 18, or the sheets 1 and 14 can bespaced apart as taught in U.S. Pat. No. 3,140,340, forming an air gapwhich provides a prism-air interface. In this construction, light raysescaping from the cube-corner sheet 1 are reflected back from beadedsheet 14, thereby providing wide angularity and divergence ofretroreflection.

Other articles of this invention are echelon or Fresnel lenses, such asthose with configurations described in U.S. Pat. Nos. 3,334,958,3,972,593, 3,511,563, and 4,082,433, and used, for example, in overheadprojectors. FIG. 6 illustrates a plurality of one type of such lens 9,viz., linear Fresnel lenses (fabricated in accordance with thisinvention, as shown herebelow) in the form of a continuous sheet 10 ofcontiguous replicated plastic lenses, which sheet can be cut to separatethe individual lenses. The flexibility and dimensional stability of theFresnel lens made in accordance with this invention makes them useful ina wide field of application, such as fdecorative mouldings, e.g.,automobile moulding, described in U.S. Pat. No. 3,908,056.

As mentioned hereinbefore, replicated shaped plastic articles can befabricated in accordance with this invention for purposes of informationprocessing and transmission. FIGS. 7 and 8 illustrate an example of sucharticles, namely a video disc 11 (the fabrication of which isexemplified hereinafter) having spirally arranged tracks 12 each ofwhich is made up of circumferentially-shaped, minute depressions orholes commonly called "micropits", with lengths, for example, about 1.2μm, widths about 0.75 μm, and depths about 0.3 μm, and which arecircumferentially spaced, for example 1.5 μm, the variations of saidlengths and spacings depending on the frequency of the carrier signalswhich are recorded on the disc, articles of this type being described inOptics & Laser Technology, supra. (Alternatively, the information on thevideo disc can be in spiral grooves with the video information appearingon the bottom and wall regions of the grooves in the form of geometricor topographical variations, as described, for example, in U.S. Pat.Nos. 3,795,534 and 3,882,214.) The high replication fidelity capabilityof this invention is particularly well-suited to fabrication of theabove-described replicated video discs.

Objects and advantages of this invention are illustrated in thefollowing examples thereof. In these examples, the parts referred to areparts by weight and the percents referred to are percents by weight. Inall runs in which the addition polymerizable oligomer products weresynthesized, a dry air atmosphere was maintained during the course ofreaction. The cured film test samples used for measuring physicalproperties were made by mixing 100 parts of the oligomer product (oroligomer product diluted with diluent monomer) with 0.5 part2,2-diethoxyacetophenone photoinitiator, vacuum degassing the resultingmixture to remove entrapped air, and casting the mixture to a thicknessof 250 microns (using a flat-bed knife coater) between two sheets of125-micron thick polyethylene terephthalate polyester, thereby forming a"sandwich" assembly. Using a laboratory ultraviolet processor (viz., a"QC Processor", manufactured by Radiation Polymer Corp.), the "sandwich"assembly was passed six times on a moving belt conveyor moving at 15 mper minute under a bank of two medium pressure mercury vapor arc lampsoperating at 80 watts/cm of length. The conveyor was spaced at adistance of 10 cm from the lamps. At the completion of the curingprocess, the cast mixture cured to a solid film of crosslinked polymerbetween the polyester sheets, which were then stripped from the polymerfilm and physical properties of the film were then tested.

The replicated diffraction grating test samples (used for measuringreplicated fidelity and thermal dimensional stability) were made in thefollowing samples by using a high frequency holographic metal molddiffraction grating master, having 867.7 line pairs per millimeter. Thismaster was coated (by a flat-bed knife coater) with a 375-micron thicklayer of the oligomer product (or oligomer product diluted with diluentmonomer), to which 0.5 percent 2,2-diethoxyacetophenone had been added.A polyethylene terephthalate polyester film (125-micron thick) wasplaced as a cover sheet over the layer of curable oligomer material andthe resulting construction was cured with said "QC Processor" by placingit on a conveyor moving at 15 meters per minute under two mediumpressure mercury vapor lamps operating at 80 watts per cm of length. Adistance between the lamps and the oligomer surface of 10 cm wasmaintained. After six passes under the lamps, polymerization of theoligomer product was complete. The polyester cover sheet was strippedoff and the layer of polymerized product (a replicated diffractiongrating) was separated from the master and used as a test sample. Thefirst order diffraction efficiency of the test sample was measured bythe procedure described by Beesley et al in J. Applied Optics. Vol. 9,No. 12, Dec. 1970, p. 2720, and the diffraction efficiency of the testsample was calculated. The test sample was then placed in a forced aircirculating oven at 130° C. for one hour. After this heat treatment, thefirst order diffraction efficiency was again measured and the percentdifference from the original value was taken as the measure of theresistance of the test sample to thermal distortion.

The diffracting grating test samples were also used to determine the gelswell of the crosslinked polymers as an indication of the degree ofcrosslinking thereof (although the gel swell of the cured film samplescould also have been used for this purpose). The gel swell wasdetermined by immersing a sample portion of known weight, W₁ (about 0.5g), of the diffraction grating test sample in 25 ml tetrahydrofuransolvent (analytical reagent grade) for 24 hours at about 23° C.,removing the resulting swelled sample portion, wiping or padded off theadhering film of solvent from the sample portion and quickly determiningits weight, W₂. The used solvent was evaporated to dryness and theweight, W₃, of the dried residue (the solubilized fraction of the sampleportion) was determined. The weight percent gel swell of the testedcrosslinked polymer was calculated by the formula: ##EQU1## The lowerthe percent gel swell, the greater the degree of crosslinking (see"Encyclopedia of Polymer Technology", Vol. 4, p. 63-65, published byInterscience Pub. (1966)).

EXAMPLE 1

Into a 1-liter metal reactor, equipped with a propeller agitator, thermmeter, addition funnel, and dry air sparger extending into the reactorthrough the lid thereof, were charged 200 g (0.25 mole)poly(dimethylsiloxane)diol silicone fluid ("Dow Corning" Q4-3557), 210 g(1.60 moles) 2-hydroxyethyl methacrylate, and 0.3 g of dibutyltindilaurate. The mixture was heated to 65° C. and 220 g (0.99 mole)isophorone diisocyanate (IPDI") was added over a two-hour period. Thereaction was complete in 16 hours as determined by infrared analysis forisocyanate. The resulting acrylate-capped polysiloxane urethane oligomerproduct had a structure essentially that of formula XXI. Eighty parts ofthe oligomer product was diluted with 20 parts 2-(N-butylcarb myl)ethylmethacrylate diluent monomer and the diluted oligomer product was curedto form film and diffraction grating test samples, the properties ofwhich are set forth in TABLE III.

EXAMPLE 2

Into a 1-liter reactor, equipped as described in Example 1, was charged157 g (0.60 mole) methylenebis(4-cyclohexylisocyanate) ("Hylene" WS).Then, while stirring, there were added, over a period on one hour, amixture of 288 g (0.12 mole) poly(dimethylsiloxane)diol silicone fluid("Dow Corning" Q4-3667) and 1.83 g (0.03 mole) 2-aminoethanolchain-extender, and the temperature of the resulting mixture was allowedto rise to 70° C. The reaction was allowed to proceed for an additionalhour at which time 131 g (1.00 mole) 2-hydroxymethyl methacrylate wasadded to the resulting isocyanate-terminated, chain-extended,urea-urethane prepolymer product. The mixture was held at 70° C. and thereaction was complete in 12 hours as determined by infrared analysis,whereupon 248 g (1.08 moles) 2-(N-butylcarbamyl)ethyl methacrylatediluent monomer was added. Infrared analysis verified that the resultingacrylate-capped, chain-extended, polycaprolactone urea-urethane oligomerproduct (excluding the diluent monomer) had essentially the structure offormula XXXIII. Cured film and diffraction grating test samples wereprepared and their compositions and properties are set forth in TableIII.

EXAMPLE 3

Into a 1-liter reaction vessel, equipped as in Example 1, were charged120 g (0.46 mole) methylenebis(4-cyclohexylisocyanate) ("Hylene" WS) and0.25 g of dibytyltin dilaurate, and the mixture heated to 65°-70° C.while stirring. There was then added over a period of one hour a mixtureof 219 g (0.091 mole) poly(dimethylsiloxane)diol silicone fluid ("DowCorning" Q4-3667) and 46 g (0.023 mole) poly(oxypropylene)diamine("Jeffamine" D-2000) and the resulting mixture heated with stirring foran additional hour at 70° C. To the stirring mixture containing theresulting isocyanate-terminated, polysiloxane-polyether, urea-urethaneprepolymer product was added 131 g (1 mole) 2-hydroxyethyl methacrylateand the resulting mixture was heated for three hours whereupon it wasfound by infrared analysis that all the isocyanate therein haddisappeared. As verified by infrared analysis, the resultingacrylate-capped, polysiloxane-polyether, urea-urethane oligomer producthad essentially the structure of formula XXXII.

Films and diffraction grating test samples were prepared using 70 partsof the above oligomer product diluted with 30 parts2-(N-butylcarbamyl)ethyl methacrylate, the compositions and propertiesof these articles being set forth in TABLE III.

EXAMPLE 4

In a 4-liter reactor, equipped as in Example 1, a mixture of 15.1 g(0.13 mole) 1,6-hexamethylenediamine and 1250 g (0.52 mole)poly(dimethylsiloxane)diol silicone fluid ("Dow Corning" Q4-3667) wasadded during a one-hour period to a mixture of 572 g (2.58 mole)isophorone diisocyanate ("IPDI") and 2 g of dibutyltin dilaurate whilemaintaining the temperature of the reactor contents at 65°-70° C. Themixture was heated at this temperature for an additional two hours toobtain the isocyanate-terminated polysiloxane, urea-urethane prepolymerproduct, and 536 g (2.76 moles) 2-hydroxyethyl methacrylate was thenadded over a one hour period. The resulting mixture was allowed to reactat 65°-70° C. until the disappearance of isocyanate, as determined byinfrared analysis, was observed, the period of reaction so requiredbeing 48 hours. Infrared analysis verified that the resultingacrylate-capped, polyester, urea-urethane oligomer product hadessentially the structure of formula XXIV. The mixture was cooled, 593 g(2.57 moles) 2-N-butylcarbamyl)ethyl methacrylate diluent monomer wasadded, and film and diffraction grating test samples were prepared fromthe diluted oligomer product, the compositions and properties of thesearticles being set forth in Table III.

                                      TABLE III                                   __________________________________________________________________________                   Physical properties                                                                              First order                                 Cured product  of cured film.sup.(a)                                                                            diffraction efficiency                                                                    Optical                         composition (calc)                                                                           Tensile                                                                            Elastic   Gel         Change                                                                            Properties.sup.(b)              Amount of Segments, %                                                                        strength                                                                           modulus                                                                            Elonga-                                                                            swell                                                                             Before                                                                            After                                                                             upon                                                                              Transmis-                       Ex.                                                                              "S"                                                                              "H"                                                                              "Linking"                                                                           kg/cm.sup.2                                                                        kg/cm.sup.2                                                                        tion %                                                                             wt. %                                                                             heating                                                                           heating                                                                           heating                                                                           sion %                                                                              Haze                      __________________________________________________________________________                                                        %                         1  25.4                                                                             27.9                                                                             46.7  240  4600  9   76  27.6                                                                              25.8                                                                              -6.5                                                                              91.2  1.4                       2  34.9                                                                             19.2                                                                             45.9  170  3200 24   --  26.3                                                                              25.9                                                                              -1.6                                                                              91.9  1.8                       3  36.0                                                                             16.3                                                                             47.7  160  2900 51   81  25.5                                                                              25.4                                                                              -0.3                                                                              91.8  3.4                       4  42.1                                                                             19.8                                                                             38.1  150  2300 28   85  23.8                                                                              23.8                                                                              0   90.1  8.2                       __________________________________________________________________________     .sup.(a) These properties were determined according to ASTM D 1708, using     a crosshead speed of 12in/min (30cm/min).                                      .sup.(b) These properties were determined according to ASTM D 1003.     

Various modifications and alterations of this invention will becomeapparent to those skilled in the art without departing from the scopeand spirit of this invention.

What is claimed is:
 1. An article comprising a shaped, plastic,optically homogeneous, cast, monolithic layer having a replicatedmicrostructure-bearing surface having a plurality of utilitariandiscontinuities and comprising a crosslinked polymer composed of (1) aplurality of hard segments of mono- or polyvalent moieties containingone or more carbocyclic and/or heterocyclic groups, and (2) a pluralityof soft segments of polyvalent polysiloxane moieties.
 2. An articleaccording to claim 1 wherein each of said moieties of said hardsegments, when their valences are satisfied by protons, has at least onemajor transition temperature above 250° K., and wherein each of saidmoieties of said soft segments has a number average molecular weight ofabout 500 to 5000 and homopolymers thereof have a glass transitiontemperature below 250° K.
 3. An article according to claim 1 whereinsaid crosslinked polymer has a gel swell within the range of 35 to 200weight percent.
 4. An article according to claim 1 wherein saidcrosslinked polymer has 10 to 80 weight percent of said hard segmentsand 10 to 60 weight percent of said soft segments.
 5. An articleaccording to claim 1 wherein said crosslinked polymer has dynamic shearmoduli, over the temperature range of 23° C. to 120° C., which fall onor within the boundary of A-B-C-D of FIG.
 1. 6. An article according toclaim 1 wherein a diffraction grating of said crosslinked polymer has afirst order diffraction efficiency which changes less than 15% whenheated at 130° C. for 1 hour as compared to the first order diffractionefficiency before heating.
 7. An article according to claim 1 whereinsaid microstrcutre-bearing surface has an average profile which isplano, convex, concave, aspheric, or combinations thereof, the heightsof said discontinuities deviating from said average profile by ±0.005 μmto ±750 μm, said discontinuities being the same or different and spacedapart or contiguous in a random or ordered manner.
 8. A shaped plasticarticle comprising a shaped, plastic, optically homogeneous, cast,monolithic layer having a replicated microstructure-bearing surfacehaving a plurality of utilitarian discontinuities and consistingessentially of crosslinked polymer composed of (1) a plurality of hardsegments of mono- or polyvalent moieties containing one or morecarbocyclic and/or heterocyclic groups and difunctional linking groupswith hydrogen bonding capability, and (2) a plurality of soft segmentsof polyvalent polysiloxane moieties, wherein each of said moieties ofsaid hard segments, when their valences are satisfied by protons, has atleast one major transition temperature above 250° K., and wherein eachof said moieties of said soft segments has a number average molecularweight of about 500 to 5000 and homopolymers thereof have a glasstransition temperature below 250° K., said crosslinked polymer having agel swell within the range of 35 to 200 weight percent, 10 to 80 weightpercent of said hard segments and 10 to 60 weight percent of said softsegments, and dynamic shear moduli, over the temperature range of 23° C.to 120° C., which fall on or within the boundary of A-B-C-D of FIG. 1,and wherein a diffraction grating of said crosslinked polymer has afirst order diffraction efficiency which changes less than 15% whenheated to 130° C. for 1 hour as compared to the first order diffractionefficiency before heating.
 9. An article according to claim 1 in theform of a retroreflective sheet comprising an array of cube-corner prismelements.
 10. An article according to claim 1 wherein said crosslinkedpolymer is formed upon radiation of an oligomeric composition comprisingone or more oligomers having (1) one or more like or different hardsegments each comprising a mono- or poly-valent moiety containing one ormore carbocyclic and/or heterocyclic groups, (2) one or more like ordifferent soft segments each comprising a poly-valent polysiloxanemoiety, and (3) one or more like or different monovalent moietiescontaining a radiation sensitive, addition-polymerizable, functionalgroup selected from the group consisting of acrylyl, methacrylyl, allyl,and vic-epoxy.
 11. An article according to claim 1 in the form of avideo disc.
 12. An article according to claim 1 in the form of adiffraction grating.
 13. An article according to claim 1 in the form ofan ophthalmic lens.
 14. An article according to claim 1, wherein saidhard segments are represented by one or more of the following formulas:##STR44## where each A is independently --NH-- or --O--,each B is(CH₂)_(f), --CO--, (CH₂)CO-- or (CH₂)_(f) --OC(O)(CH₂)_(f)C(O)O(CH₂)_(f), where f is an integer of 2 to 5, each R² isindependently hydrogen or a lower alkyl, each R³ is independently adi-valent carbocyclic-containing radical derived from benzene,napthalene, cyclohexane, dicyclohexylmethane, diphenylmethane ornorbornene, and their lower alkyl-substituted derivatives, by removal oftwo of their hydrogen atoms, each R⁴ is independently an alkylene moietywith 2 to 10 carbon atoms, or a cycloalkylene moiety with 6 to 10 carbonatoms, each R⁵ is independently a phenyl moiety or methyl, each R⁶ isindependently a lower alkyl with 1 to 4 carbon atoms,g is zero or anumber up to 5, h is an integer of 1 to 10, h' is zero or an integer of1 to 10, each d, d' and d" is independently zero and 1, with the provisothat if either one of d' or d" is 1, then the other is zero,and whereinsaid soft segments are residues remaining from removal of the activehydrogen atoms of polysiloxane polyols.
 15. An article according toclaim 14 wherein said soft segments are represented by one or more ofthe following formulas: ##STR45## where b' is a number of 6 to 35, and Ris a linear or branched alkylene group having 1 to 12 carbon atoms or apolyoxyalkylene group having 4 to 80 carbon atoms and 1 to 40 oxygenatoms, and ##STR46## where the groups enclosed by the single bracketswith subscripts b' and c' are repeating units randomly distributedwithin the double bracket, b' being a number of 6 to 35 and c' being 2or 3, and R is as defined above.
 16. An article according to claim 1wherein said hard segments are represented by the formula: ##STR47##where each A is independently --NH-- or --O-- each R³ in independently adi-valent carbocyclic-containing radical derived from benzene,napthalene, cyclohexane, dicyclohexylmethane, diphenylmethane, ornorbornene, and their lower alkyl-substituted derivatives, by removal oftwo of their hydrogen atoms,each R is independently an alkylene moietywith 2 to 10 carbon atoms, or a cycloalkylene moiety with 6 to 10 carbonatoms, g is zero or a number up to 5, and each d is independently zeroor 1,and said soft segments are represented by one of the followingformulas: ##STR48## where b' is a number of 6 to 35, and R is a linearor branched alkylene group having 1 to 12 carbon atoms or apolyoxyalkylene group having 4 to 80 carbon atoms and 1 to 40 oxygenatoms, and ##STR49## where the groups enclosed by the single bracketswith subscripts b' and c' are repeating units randomly distributedwithin the double bracket, b' being a number of 6 to 35 and c' being 2or 3, and R is as defined above.
 17. An article according to claim 1wherein said hard segments comprise those represented by the formula:##STR50## and said soft segments comprise those represented by thefollowing formula ##STR51##
 18. An article according to claim 1 whereinsaid hard segments comprise those represented by the formula: ##STR52##and said soft segments comprise those represented by the formula:##STR53##
 19. An article according to claim 1 wherein said hard segmentscomprise those represented by the formula: ##STR54## and said softsegments comprise those represented by the following formula: ##STR55##20. An article according to claim 1 wherein said hard segments comprisethose represented by the formula: ##STR56## and said soft segmentscomprise that those represented by the following formula: ##STR57## 21.A plastic diffraction grating comprising a shaped, plastic, monolithiclayer having a diffraction grating-bearing surface and comprisingcrosslinked polymer composed of(1) 20 to 50 weight percent of aplurality of hard segments selected from those represented by one orboth of the formulas: ##STR58## where each A is independently --NH-- or--O--, A' is --NH--, each R³ is independently a di-valentcarbocyclic-containing radical derived from benzene, napthalenecyclohexane, dicyclohexylmethane, or diphenylmethane, and their loweralkyl-substituted derivatives, by removal of two of their hydrogenatoms, each R⁴ is independently an alkylene moiety with 2 or 4 carbonatoms, or a cycloalkylene moiety with 6 to 10 carbon atoms, each R⁵ isphenyl, each d is independently zero or 1g is zero or a number having anaverage of 1 to 3, and h' is zero or an integer of 1 to 10,(2) 15 to 45weight percent of a plurality of soft segments selected from thoserepresented by one or more of the formulas: ##STR59## where b' is anumber of 6 to 35, and R is a linear or branched alkylene group having 1to 12 carbon atoms or a polyoxyalkylene group having 4 to 80 carbonatoms and 1 to 40 oxygen atoms, and ##STR60## where the groups enclosedby the single brackets with subscripts b' and c' are repeating unitsrandomly distributed within the double bracket, b' being a number of 6to 35 and c' being 2 or 3, and R is alkylene as defined above, saidcrosslinked polymer having a gel swell within the range of 35 to 200weight %, and dynamic shear moduli, over a temperature range of 23° to120° C., which fall on or within the boundary of A-B-C-D of FIG. 1, andwherein the first order diffraction efficiency of said grating changesless than 5% when heated at 130° C. for 1 hour as compared to the firstorder diffraction efficiency before heating.
 22. A process for making ashaped plastic article comprising a shaped, plastic, monolithic layerhaving a microstructure-bearing surface and comprising crosslinked,polymer, comprising the steps of filling a mold master with a fluid,castable, one-part radiation addition-polymerizable, crosslinkable,oligomeric composition or precursors thereof, said oligomericcomposition comprising one or more oligomers having (1) one or more likeor different hard segments each comprising a mono- or poly-valent moietycontaining one or more carbocyclic and/or heterocyclic groups, (2) oneor more like or different soft segments each comprising poly-valentpolysiloxane moiety, and (3) one or more like or different monovalentmoieties containing a radiation sensitive, addition polymerizable,functional group selected from the group consisting of acrylyl,methacrylyl, allyl, and vic-epoxy, exposing the resulting castoligomeric composition, or precursors thereof, to radiation, andrecovering said shaped plastic article.
 23. The process according toclaim 22 wherein said oligomeric composition contains 10 to 80 weightpercent of said hard segments and 10 to 60 weight percent of said softsegments, said hard segments containing difunctional linkages withhydrogen-bonding capability, each of said moieties of said hardsegments, with its valences satisfied by protons, having at least onemajor transition temperature above 250° K., each of said moieties ofsaid soft segments having a number average molecular weight of about 500to 5000 and homopolymers thereof having a glass transition temperaturebelow 250° K., said crosslinked polymer having a gel swell within therange of 35 to 200 weight percent and having dynamic shear moduli, overthe temperature range of 23° to 120° C., which fall on or within theboundary of A-B-C-D of FIG. 1, and wherein a diffraction grating of saidcrosslinked polymer has a first order diffraction efficiency whichchanges less than 15% when heated at 130° C. for 1 hour as compared tothe first order diffraction efficiency before heating.
 24. The processaccording to claim 22 wherein said microstructure-bearing surface has anaverage profile which is plano, convex, concave, aspheric, orcombinations thereof, said surface having discontinuities whose heightsdeviate from said average profile by ±0.005 μm to ±750 μm, said surfacesbeing free of utilitarian discontinuities or having one or a pluralityof utilitarian discontinuities which are the same or different andspaced apart or contiguous in a random or ordered manner.
 25. Theprocess according to claim 22 wherein said article is in the form of adiffraction grating.
 26. The process according to claim 22 wherein saidarticle is in the form of a retroreflective sheet comprising an array ofcube-corner prism elements.
 27. The process according to claim 22wherein said article is in the form of a Fresnel or echelon lenselement.
 28. The process according to claim 22 wherein said article isin the form of a video disc.
 29. The process according to claim 22wherein said article is in the form of a precision optical element. 30.The process according to claim 22 wherein said article is in the form ofan ophthalmic lens.
 31. The process according to claim 22 wherein saidoligomers are represented by the formula: ##STR61## where α is 1 or 2βis zero or a number up to 20 and has an average value up to about 5 γ is2 or 3 "E" is represented by one or more of the formulas: ##STR62##where R¹ is hydrogen atom or methyl,each A is independently --NH-- or--O--, a, b, c and d are each independently zero or 1, with the provisosthat(1) at least one of b and d must be 1, (2) if b and c are both zero,then a and d must be 1, (3) if b and d are both 1, then a and c must be1, and e is at least 2, and (4) if d is 1 and a and b are both zero,then c must be 1, e is an integer of 1 to 5, ##STR63## where d is zeroor 1,e is an integer of 1 to 5, ##STR64## R² is hydrogen or a loweralkyl B is (CH₂)_(f), --CO--, (CH₂)_(e) CO-- or (CH₂)_(f) OC(O)(CH₂)_(f)C(O)O(CH₂)_(f), where each f is an integer of 2 to 5, and each d isindependently zero or 1,"H" is represented by one or more of theformulas: ##STR65## or, when "R" is an ethylenically unsaturated moietyof the formula first depicted above, ##STR66## where each A isindependently --NH-- or --O--, each B is (CH₂)_(f), --CO--, --(CH₂)CO--or (CH₂)_(f) --OC(O)(CH₂)_(f) C(O)O(CH₂)_(f), where f is an integer of 2to 5, each R² is independently hydrogen or a lower alkyl, each R³ isindependently a polyvalent carbocyclic-containing radical derived frombenzene, naphthalene, cyclohexane, dicyclohexymethane, diphenylmethaneor norbornene, and their lower alkyl-substituted derivatives, by removalof two or more of their hydrogen atoms, each R⁴ is independently analkylene moiety with 2 to 10 carbon atoms, or a cycloalkylene moietywith 6 to 10 carbon atoms, each R⁵ is independently a phenyl moiety ormethyl each R⁶ is independently a lower alkyl with 1 to 4 carbon atoms,gis zero or a number up to 5, h is an integer of 1 to 10 h' is zero or aninteger of 1 to 10, each d, d' and d" is independently zero or 1, withthe proviso that if either one of d' or d" is 1, then the other is zero,and"S" is the residue remaining after removal of the active hydrogenatoms of polysiloxane polyols.
 32. The process according to claim 31wherein"E" is represented by one or more of the formulas: ##STR67##where R¹ is methyl and A is --O--, ##STR68## where R¹ is methyl, A is--O--, and e is 2, ##STR69## where R¹ is hydrogen and A is --O--, and"S" is ##STR70## where b' is a number of 6 to 35, and R is a linear orbranched alkylene group having 1 to 12 carbon atoms or a polyoxalkylenegroup having 4 to 80 carbon atoms and 1 to 40 oxygen atoms, and##STR71## where the groups enclosed by the single brackets withsubscripts b' and c' are repeating units randomly distributed within thedouble bracket, b' being a number of 6 to 35 and c' being 2 or 3, and Ris as defined above.
 33. A shaped, plastic article made by the processof claim
 22. 34. An article according to claim 1 wherein the heights ofsaid discontinuities deviate from the average profile of said surface by±0.1 μm to ±750 μm, said discontinuities being the same or different andspaced apart or continguous in a random or ordered manner, and whereinsaid polymer has optical homogenity manifested by at least 91%transmission of light, haze of less than 5%, and birefringence, Δρ, ofless than 0.002.
 35. An article according to claim 1 in the form of aFresnel lens element.
 36. An article according to claim 1 in the form ofan echelon lens element.
 37. An article according to claim 8 whereinsaid difunctional linking groups are carbonyldioxy, carbamato, ureylene,amido, or oxy.